Pt Dopant: Controlling the Ir Oxidation States toward Efficient and Durable Oxygen Evolution Reaction in Acidic Media

Extra Form
author Kwangyeol Lee
journal Advanced Functional Materials
Homepage http://nanolab.korea.ac.kr/
?

단축키

Prev이전 문서

Next다음 문서

ESC닫기

크게 작게 위로 아래로 댓글로 가기 인쇄

최송아.jpg

최송아 (제1저자, 석박통합과정)

Dissolution of Ir oxides in Ir‐based catalysts, which is closely linked to the catalyst activity and stability toward the oxygen evolution reaction (OER) in acidic media, is a critical unresolved problem in the commercialization of water electrolysis. Doping foreign elements into the Ir oxides can accomplish an optimal combination of Ir oxidation states that is conducive to the leaching‐resistance of active catalytic sites. Here, it is reported that Pt doping into IrOx‐based nanoframe is beneficial in both terms of activity and stability. The Pt‐doped IrOx‐based nanoframe achieves the mass activity of 0.644 A mg−1Ir+Pt at 1.53 V RHE, which is 15‐fold higher than that of the commercial IrO2. During the accelerated durability test, the IrIV‐to‐IrIII ratio of 5 is maintained in the presence of Pt dopant to effectively mitigate the degradation of Ir catalyst, leading to the superb catalyst durability in acidic media

TOC.jpg


 https://doi.org/10.1002/adfm.202003935


Articles

1 2 3 4 5 6 7 8 9