5월 10일(목) 대학원 세미나 정옥상 교수(부산대학교 화학과)

by 관리자 posted May 03, 2018
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초청강사 정옥상 교수
소속 부산대학교 화학과
일시 2018년 5월 10일 (목) 오후 5시
장소 아산이학관 331호

Porous Crystalline Matrix for Task-Specific Functions

The self-assemblies of metal cations with new multi-dentate ligands produce various porous crystalline matrix such as metalorganic nanotube (MONT), metalorganic frameworks (MOFs), zeolite L-mimic metalorganic framework (ZLMOF), and nanotube.(NT) showing the following functions:


1. The advanced triple-functions as a reservoir for unstable reactants, a photoreaction platform, and a byproduct-scavenger.

2. The hydrophobic nano-channel that effectively adsorbs a wide range of fused aromatic hydrocarbons (FAHs) for energy-transfer materials.

3. Trapping agents of an iodomethyl radical (·CH2I) via single crystal-to-single crystal photoreaction without destruction of the suprachannel.

4. Crystalline matrix for molecular structure determination of a wide range of liquid chemicals via single-crystal-to-single-crystal (SCSC) guest exchange.

5. Confined catalysts

 

References

Angew.Chem.Int. Ed. 2015, 54, 9284 9288

Chem. Commun., 2016, 52, 25452548.

Chem. Commun., 2014, 50, 74517454.

Cryst. Growth Des. 2016, 16, 30543058.

Cryst. Growth Des. 2017, 17, 6677-6683.

Acc. Chem. Res. 2016, 49, 18351843.



20180510_세미나_정옥상 교수.pdf