5월 10일(목) 대학원 세미나 정옥상 교수(부산대학교 화학과)
| 초청강사 | 정옥상 교수 |
|---|---|
| 소속 | 부산대학교 화학과 |
| 일시 | 2018년 5월 10일 (목) 오후 5시 |
| 장소 | 아산이학관 331호 |
Porous Crystalline Matrix for Task-Specific Functions
The self-assemblies of metal cations with new multi-dentate ligands produce various porous crystalline matrix such as metal–organic nanotube (MONT), metal–organic frameworks (MOFs), zeolite L-mimic metal–organic framework (ZLMOF), and nanotube.(NT) showing the following functions:
1. The advanced triple-functions as a reservoir for unstable reactants, a photoreaction platform, and a byproduct-scavenger.
2. The hydrophobic nano-channel that effectively adsorbs a wide range of fused aromatic hydrocarbons (FAHs) for energy-transfer materials.
3. Trapping agents of an iodomethyl radical (·CH2I) via single crystal-to-single crystal photoreaction without destruction of the suprachannel.
4. Crystalline matrix for molecular structure determination of a wide range of liquid chemicals via single-crystal-to-single-crystal (SCSC) guest exchange.
5. Confined catalysts
References
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Acc. Chem. Res. 2016, 49, 1835−1843.